54. "Substrate-specific activation and long-range olefin migration catalysis at the Pd centers in a porous metal-macrocycle framework"
M. Han, S. Tashiro,* T. Shiraogawa, M. Ehara,* and M. Shionoya*
Bull. Chem. Soc. Jpn. 95, 1303–1307 (2022). (Selected paper, inside cover)
https://doi.org/10.1246/bcsj.20220185

53. "Highly selective acid-catalyzed olefin isomerization of limonene to terpinolene by kinetic suppression of overreactions in a confined space of porous metal-macrocycle frameworks"
W. He, S. Tashiro,* and M. Shionoya*
Chem. Sci. 13, 8752–8758 (2022). (Inside front cover)
https://doi.org/10.1039/d2sc01561g

52. "Orientational isomerisation of guest molecules in equilibrium in a tubular host crystal formed via halogen and hydrogen bonding"
Y. Yamashita, S. Tashiro,* and M. Shionoya*
CrystEngComm 24, 1518–1522 (2022). (Back cover)
https://doi.org/10.1039/D1CE01654G

51. "Shape-selective one-step synthesis of branched gold nanoparticles on the crystal surface of redox-active PdII-macrocycles"
Y. Yamashita, S. Tashiro,* Y. Ishii, T. Uchihashi, N. Matsushita, R. Kubota, and M. Shionoya*
Dalton Trans. 51, 1318–1324 (2022). (Outside front cover, HOT article)
https://doi.org/10.1039/d1dt03973c

50. "Site-selective binding of terpenoids within a confined space of metal–macrocycle framework: Substrate-specific promotion or inhibition of cyclization reactions"
S. Tashiro,* W. He, R. Hayashi, Y. Lin, and M. Shionoya*
Org. Chem. Front. 8, 4071–4077 (2021). (Inside front cover)
https://doi.org/10.1039/d1qo00750e

49. "Phase-Dependent Reactivity and Host-Guest Behaviors of a Metallo-Macrocycle in Liquid and Solid-State Photosensitized Oxygenation Reactions"
K. Omoto, S. Tashiro, and M. Shionoya*
J. Am. Chem. Soc. 143, 5406–5412 (2021). (Front cover)
https://pubs.acs.org/doi/10.1021/jacs.0c13338

48. "Mechanistic Studies on Photoinduced Catalytic Olefin Migration Reactions at the Pd(II) Centers of a Porous Crystal, Metal-Macrocycle Framework"
H. Yonezawa, T. Shiraogawa, M. Han, S. Tashiro, M. Ehara, and M. Shionoya*
Chem. Asian J. 16, 202–206 (2021). (Front cover)
https://doi.org/10.1002/asia.202001306

47. "Face-selective adsorption of a prochiral compound on the chiral pore-surface of metal-macrocycle framework (MMF) directed towards stereoselective reactions"
S. Tashiro,* T. Umeki, R. Kubota, and M. Shionoya*
Faraday Discuss. 225, 197–209 (2021).
https://doi.org/10.1039/d0fd00019a

46. "Multipoint Hydrogen Bonding-based Molecular Recognition of Amino Acids and Peptide Derivatives in a Porous Metal-Macrocycle Framework: Residue-Specificity, Diastereoselectivity, and Conformational Control"
S. Tashiro,* K. Nakata, R. Hayashi, and M. Shionoya*
Small 17, 2005803 (2021). (Frontispiece)
https://doi.org/10.1002/smll.202005803

45. "Protonation-induced self-assembly of bis-phenanthroline macrocycles into nanofibers arrayed with tetrachloroaurate, hexachloroplatinate or phosphomolybdate ions"
S. Tashiro,* S. Shimizu, M. Kuritani, and M. Shionoya*
Dalton Trans. 49, 13948–13953 (2020). (Back cover)
https://doi.org/10.1039/d0dt03287e

44. "Novel Porous Crystals with Macrocycle-Based Well-Defined Molecular Recognition Sites"
S. Tashiro, and M. Shionoya*
Acc. Chem. Res. 53, 632–643 (2020). (Supplementary Cover Art)
https://dx.doi.org/10.1021/acs.accounts.9b00566

43. "Core-shell metal-macrocycle framework (MMF): spatially selective dye inclusion through core-to-shell anisotropic transport along crystalline 1D-channels connected by epitaxial growth"
S. Tashiro,* S. Mitsui, D. W. Burke, R. Kubota, N. Matsushita, and M. Shionoya*
CrystEngComm 22, 1306–1309 (2020). (Back cover)
https://doi.org/10.1039/d0ce00120a

42. "Molecular recognition of planar and non-planar aromatic hydrocarbons through multipoint Ag–π bonding in a dinuclear metallo-macrocycle"
K. Omoto, S. Tashiro, and M. Shionoya*
Chem. Sci. 10, 7172–7176 (2019). (Inside back cover)
https://doi.org/10.1039/c9sc02619c

41. "Formation and characterization of charge coupled structure of polyoxometalate particles and a GaAs-based nanowire for readout of molecular charge states"
K. Sasaki, S. Okamoto, S. Tashiro, T. Asai, and S. Kasai*
Jpn. J. Appl. Phys. 58, SDDE13 (2019).
https://doi.org/10.7567/1347-4065/ab09d1

40. "Preferential Photoreaction in a Porous Crystal, Metal–Macrocycle Framework: PdII-Mediated Olefin Migration over [2+2] Cycloaddition"
H. Yonezawa, S. Tashiro, T. Shiraogawa, M. Ehara, R. Shimada, T. Ozawa, and M. Shionoya*
J. Am. Chem. Soc. 140, 16610–16614 (2018).
https://doi.org/10.1021/jacs.8b08534

39. "Rational Synthesis of Benzimidazole[3]arenes by CuII-catalyzed Post-macrocyclization Transformation"
S. Tashiro,* T. Umeki, R. Kubota, and M. Shionoya*
Chem. Sci. 9, 7614–7619 (2018). (Back cover)
https://doi.org/10.1039/c8sc03086c

38. "Multifunctional Octamethyltetrasila[2.2]cyclophanes: Conformational Variations, Circularly Polarized Luminescence, and Organic Electroluminescence"
M. Shimada, Y. Yamanoi,* T. Ohto, S.-T. Pham, R. Yamada, H. Tada, K. Omoto, S. Tashiro, M. Shionoya, M. Hattori, K. Jimura, S. Hayashi, H. Koike, M. Iwamura, K. Nozaki, and H. Nishihara*
J. Am. Chem. Soc. 139, 11214–11221 (2017).
https://doi.org/10.1021/jacs.7b05671

37. "Arrangement of Proteinogenic -Amino Acids on a Cyclic Peptide comprising Alternate Biphenyl-Cored -Amino Acids"
S. Tashiro,* M. Chiba, and M. Shionoya*
Chem. Asian J. 12, 1087–1094 (2017). (Inside cover)
https://doi.org/10.1002/asia.201700203

36. "Non-Covalent Immobilisation of p-Toluenesulfonic Acid in a Porous Molecular Crystal for Size-Specific Acid-Catalysed Reactions"
S. Tashiro,* H. Yonezawa, R. Kubota, T. Umeki, and M. Shionoya*
Chem. Commun. 52, 7657–7660 (2016). (Inside back cover)
https://doi.org/10.1039/c6cc02621d

35. "Chiral Metal–Macrocycle Frameworks: Supramolecular Chirality Induction and Helicity Inversion of the Helical Macrocyclic Structures"
R. Kubota, S. Tashiro, and M. Shionoya*
Chem. Sci. 7, 2217–2221 (2016).
https://doi.org/10.1039/c5sc04570c

34. "Host-Guest Interactions by Metal to Metal Dative Bonding: Recognition of Ruthenocene by a Metallo-Host"
K. Omoto, S. Tashiro, and M. Shionoya*
Z. Anorg. Allg. Chem. 641, 2056–2059 (2015).
https://doi.org/10.1002/zaac.201500630

33. "Iridium-Catalyzed Reductive Carbon–Carbon Bond Cleavage Reaction on a Curved Pyridylcorannulene Skeleton"
S. Tashiro, M. Yamada, and M. Shionoya*
Angew. Chem. Int. Ed. 54, 5351–5354 (2015).
https://doi.org/10.1002/anie.201500819

32. "Multipoint Recognition of Ditopic Aromatic Guest Molecules via Ag–π Interactions within a Dimetal Macrocycle"
K. Omoto, S. Tashiro, M. Kuritani, and M. Shionoya*
J. Am. Chem. Soc. 136, 17946–17949 (2014).
https://doi.org/10.1021/ja5106249

31. "In Situ X-ray Snapshot Analysis of Transient Molecular Adsorption in a Crystalline Channel"
R. Kubota, S. Tashiro, M. Shiro, and M. Shionoya*
Nat. Chem. 6, 913–918 (2014).
https://doi.org/10.1038/NCHEM.2044

30. "Simultaneous Arrangement of up to Three Different Molecules on the Pore Surface of a Metal–Macrocycle Framework: Cooperation and Competition"
S. Tashiro, T. Umeki, R. Kubota, and M. Shionoya*
Angew. Chem. Int. Ed. 53, 8310–8315 (2014). (Frontispiece)
https://doi.org/10.1002/anie.201404179

29. "Cavity-Assembled Porous Solids (CAPSs) for Nanospace-Specific Functions"
S. Tashiro, and M. Shionoya*
Bull. Chem. Soc. Jpn. 87, 643–654 (2014).
https://doi.org/10.1246/bcsj.20140007

28. "Palladium- or Proton-Induced Submicro Spherical Aggregation of Macrocyclic Amphiphiles in Aqueous Solution"
S. Tashiro, R. Kubota, M. Kawagoe, and M. Shionoya*
Dalton Trans. 42, 15915–15918 (2013).
https://doi.org/10.1039/c3dt51827b

27. "Discrete and Polymeric, Mono- and Dinuclear Silver Complexes of a Macrocyclic Tetraoxime Ligand with AgI–AgI Interactions"
S. Tashiro, J. Tanihira, M. Yamada, and M. Shionoya*
Sensors 13, 5671–5685 (2013).
https://doi.org/10.3390/s130505671

26. "Stimuli-Responsive Synthetic Metallopeptides"
S. Tashiro, and M. Shionoya*
Chem. Lett. 42, 456–462 (2013). (Highlight Review)
https://doi.org/10.1246/cl.130334

25. "Organic and Organometallic Nanofibers formed by Supramolecular Assembly of Diamond-Shaped Macrocyclic Ligands and PdII Complexes"
M. Kuritani, S. Tashiro, and M. Shionoya*
Chem. Asian J. 8, 1368–1371 (2013). (Cover Picture)
https://doi.org/10.1002/asia.201300209

24. "A Cyclopalladated Complex of Corannulene with a Pyridine Pendant and its Columnar Self-Assembly"
M. Yamada, S. Tashiro, R. Miyake, and M. Shionoya*
Dalton Trans. 42, 3300–3303 (2013).
https://doi.org/10.1039/c2dt32883f

23. "Metallo-Foldamers with Backbone-Coordinative Oxime Peptides: Control of Secondary Structures"
S. Tashiro, K. Matsuoka, A. Minoda, and M. Shionoya*
Angew. Chem. Int. Ed. 51, 13123–13127 (2012).
https://doi.org/10.1002/anie.201206968

22. "Non-Covalent Surface Modification of Metal-Macrocycle Framework with Mono-Substituted Benzenes"
R. Kubota, S. Tashiro, T. Umeki, and M. Shionoya*
Supramol. Chem. 24, 867–877 (2012).
http://dx.doi.org/10.1080/10610278.2012.733394

21. "A Ternary Charge-Transfer Complex composed of Cyclotriveratrylene (CTV) and a Polyoxometalate (POM) with Quinone as an Electronic Modulator"
S. Tashiro, S. Hashida, and M. Shionoya*
Chem. Asian J. 7, 1180–1184 (2012).
https://doi.org/10.1002/asia.201200057

20. "Metal–Macrocycle Framework (MMF): Supramolecular Nano-Channel Surfaces with Shape Sorting Capability"
S. Tashiro, R. Kubota, and M. Shionoya*
J. Am. Chem. Soc. 134, 2461–2464 (2012).
https://doi.org/10.1021/ja209422m

19. "Stacked Platinum Complexes of the Magnus’ Salt Type Inside a Coordination Cage"
G. H. Clever, W. Kawamura, S. Tashiro, M. Shiro, and M. Shionoya*
Angew. Chem. Int. Ed. 51, 2606–2609 (2012).
https://doi.org/10.1002/anie.201108197

18. "Heterodinuclear Metal Arrangement in a Flat Macrocycle with Two Chemically-Equivalent Metal Chelating Sites"
M. Kuritani, S. Tashiro, and M. Shionoya*
Inorg. Chem. 51, 1508–1515 (2012).
https://doi.org/10.1021/ic201803c

17. "Chiral Recognition of -Amino Acids by an Optically Active (2S,5S,8S,11S)-2,5,8,11-Tetraethyl Cyclen Cobalt(III) Complex"
S. Tashiro, Y. Ogura, S. Tsuboyama, K. Tsuboyama, and M. Shionoya*
Inorg. Chem. 50, 4–6 (2011).
https://doi.org/10.1021/ic101760k

16. "Light-Triggered Crystallization of a Molecular Host–Guest Complex"
G. H. Clever, S. Tashiro, and M. Shionoya*
J. Am. Chem. Soc. 132, 9973–9975 (2010).
https://doi.org/10.1021/ja103620z

15. "Inducing -Helices in Short Oligopeptides through Binding by an Artificial Hydrophobic Cavity"
C. Dolain, Y. Hatakeyama, T. Sawada, S. Tashiro, and M. Fujita*
J. Am. Chem. Soc. 132, 5564–5565 (2010).
https://doi.org/10.1021/ja100585w

14. "One-Pot, Template Syntheses of a New Class of Metallomacrocycles with a Tetraoxime Cyclic Skeleton"
S. Tashiro, A. Minoda, M. Yamada, and M. Shionoya*
Inorg. Chem. 48, 10093–10101 (2009).
https://doi.org/10.1021/ic900993j

13. "Inclusion of Anionic Guests inside a Molecular Cage with Palladium(II) Centers as Electrostatic Anchors"
G. H. Clever, S. Tashiro, and M. Shionoya*
Angew. Chem. Int. Ed. 48, 7010–7012 (2009).
https://doi.org/10.1002/anie.200902717

12. "Soft Metal-Mediated Base Pairing with Novel Synthetic Nucleosides Possessing an O,S-Donor Ligand"
Y. Takezawa, K. Tanaka, M. Yori, S. Tashiro, M. Shiro, and M. Shionoya*
J. Org. Chem. 73, 6092–6098 (2008).
https://doi.org/10.1021/jo800587d

11. "Ni(II)-Mediated Self-Assembly of Artificial -Dipeptides Forming a Macrocyclic Tetranuclear Complex with Interior Spaces for In-Line Molecular Arrangement"
R. Miyake, S. Tashiro, M. Shiro, K. Tanaka, and M. Shionoya*
J. Am. Chem. Soc. 130, 5646–5647 (2008).
https://doi.org/10.1021/ja8009555

10. "Self-Assembly and Host–Guest Chemistry of a 3.5-nm Coordination Nanotube"
T. Yamaguchi, S. Tashiro, M. Tominaga, M. Kawano, T. Ozeki, and M. Fujita*
Chem. Asian J. 2, 468–476 (2007).
https://doi.org/10.1002/asia.200600429

9. "Folding of an Ala-Ala-Ala Tripeptide into a -Turn via Hydrophobic Encapsulation"
S. Tashiro, M. Kobayashi, and M. Fujita*
J. Am. Chem. Soc. 128, 9280–9281 (2006).
https://doi.org/10.1021/ja061722e

8. "Peptide Recognition: Encapsulation and -Helical Folding of a Nine-Residue Peptide within a Hydrophobic Dimeric Capsule of a Bowl-Shaped Host"
S. Tashiro, M. Tominaga, Y. Yamaguchi, K. Kato, and M. Fujita*
Chem. Eur. J. 12, 3211–3217 (2006).
https://doi.org/10.1002/chem.200501424

7. "Selective Recognition of Trp- and Tyr-Rich Oligopeptides by Self-Assembled Coordination Hosts"
S. Tashiro, and M. Fujita*
Bull. Chem. Soc. Jpn. 79, 833–837 (2006). (BCSJ Award).
https://doi.org/10.1246/bcsj.79.833

6. "Folding a De Novo Designed Peptide into an -Helix through Hydrophobic Binding by a Bowl-Shaped Host"
S. Tashiro, M. Tominaga, Y. Yamaguchi, K. Kato, and M. Fujita*
Angew. Chem. Int. Ed. 45, 241–244 (2006).
https://doi.org/10.1002/anie.200502802

5. "Sequence-Selective Recognition of Peptides within the Single Binding Pocket of a Self-Assembled Coordination Cage"
S. Tashiro, M. Tominaga, M. Kawano, B. Therrien, T. Ozeki, and M. Fujita*
J. Am. Chem. Soc. 127, 4546–4547 (2005).
https://doi.org/10.1021/ja044782y

4. "A 3.5-nm Coordination Nanotube"
T. Yamaguchi, S. Tashiro, M. Tominaga, M. Kawano, T. Ozeki, and M. Fujita*
J. Am. Chem. Soc. 126, 10818–10819 (2004).
https://doi.org/10.1021/ja047048n

3. "PdII-Directed Dynamic Assembly of a Dodecapyridine Ligand into End-Capped and Open Tubes: The Importance of Kinetic Control in Self-Assembly"
S. Tashiro, M. Tominaga, T. Kusukawa, M. Kawano, S. Sakamoto, K. Yamaguchi, and M. Fujita*
Angew. Chem. Int. Ed. 42, 3267–3270 (2003).
https://doi.org/10.1002/anie.200351397

2. "Spectroscopic and Crystallographic Studies on the Stability of Self-Assembled Coordination Nanotubes"
M. Aoyagi, S. Tashiro, M. Tominaga, K. Biradha, and M. Fujita*
Chem. Commun. 2036–2037 (2002).
https://doi.org/10.1039/B205194J

1. "Dynamic Aspects in Host-Guest Complexation by Coordination Nanotubes"
M. Tominaga, S. Tashiro, M. Aoyagi, and M. Fujita*
Chem. Commun. 2038–2039 (2002).
https://doi.org/10.1039/B205196F